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The shift of the g parallel value upon GSH addition (from 2.233 to 2.175, Table S2), as well as the change within the superhyperfine structure, is very similar to that observed for analogous thiosemicarbazone complexes, where GSH is bound equatorially to a tridentate ligand 53,54 It was further affirmed by the consistency of the simulated and experimental EPR data (Figure S18 and Table S2)